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Chemoselective Electrochemical Hydrogenation of Ketones and Aldehydes with a Well‐Defined Base‐Metal Catalyst

Hydrogenation reactions are fundamental functional group transformations in chemical synthesis. Here, we introduce an electrochemical method for the hydrogenation of ketones and aldehydes by in situ formation of a Mn‐H species. We utilise protons and electric current as surrogate for H(2) and a base...

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Detalles Bibliográficos
Autores principales: Fokin, Igor, Siewert, Inke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702145/
https://www.ncbi.nlm.nih.gov/pubmed/32497312
http://dx.doi.org/10.1002/chem.202002075