Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex

The synthesis and organometallic chemistry of rhodium(I) complex [Rh(CNC–Me)(SOMe(2))][BAr(F) (4)], featuring NHC‐based pincer and labile dimethyl sulfoxide ligands, is reported. This complex reacts with biphenylene and chlorobenzene to afford products resulting from selective C–C and C–Cl bond acti...

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Detalles Bibliográficos
Autores principales: Kynman, Amy E., Lau, Samantha, Dowd, Sean O., Krämer, Tobias, Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702176/
https://www.ncbi.nlm.nih.gov/pubmed/33328794
http://dx.doi.org/10.1002/ejic.202000780

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702176/
https://www.ncbi.nlm.nih.gov/pubmed/33328794
http://dx.doi.org/10.1002/ejic.202000780

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