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Oxidative Addition of Biphenylene and Chlorobenzene to a Rh(CNC) Complex
The synthesis and organometallic chemistry of rhodium(I) complex [Rh(CNC–Me)(SOMe(2))][BAr(F) (4)], featuring NHC‐based pincer and labile dimethyl sulfoxide ligands, is reported. This complex reacts with biphenylene and chlorobenzene to afford products resulting from selective C–C and C–Cl bond acti...
Autores principales: | Kynman, Amy E., Lau, Samantha, Dowd, Sean O., Krämer, Tobias, Chaplin, Adrian B. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7702176/ https://www.ncbi.nlm.nih.gov/pubmed/33328794 http://dx.doi.org/10.1002/ejic.202000780 |
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