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High pressure synthesis of phosphine from the elements and the discovery of the missing (PH(3))(2)H(2) tile

High pressure reactivity of phosphorus and hydrogen is relevant to fundamental chemistry, energy conversion and storage, and materials science. Here we report the synthesis of (PH(3))(2)H(2), a crystalline van der Waals (vdW) compound (I4cm) made of PH(3) and H(2) molecules, in a Diamond Anvil Cell...

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Detalles Bibliográficos
Autores principales: Ceppatelli, Matteo, Scelta, Demetrio, Serrano-Ruiz, Manuel, Dziubek, Kamil, Garbarino, Gaston, Jacobs, Jeroen, Mezouar, Mohamed, Bini, Roberto, Peruzzini, Maurizio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7705733/
https://www.ncbi.nlm.nih.gov/pubmed/33257669
http://dx.doi.org/10.1038/s41467-020-19745-2