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Synthesis of Functionally Substituted Bicyclo[4.2.1]nona-2,4-dienes and Bicyclo[4.2.1]nona-2,4,7-trienes by Cobalt(I)-catalyzed [6π + 2π] Cycloaddition of 2-Tropylcyclohexanone

[Image: see text] The [6π + 2π] cycloaddition of 2-tropylcyclohexanone to allenes and alkynes was accomplished for the first time using the three-component catalytic system Co(acac)(2)(dppe)/Zn/ZnI(2), thus giving previously unknown functionally substituted bicyclo[4.2.1]nona-2,4-dienes and bicyclo[...

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Detalles Bibliográficos
Autores principales: Kadikova, Gulnara N., Dzhemileva, Lilya U., D’yakonov, Vladimir A., Dzhemilev, Usein M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7726926/
https://www.ncbi.nlm.nih.gov/pubmed/33324856
http://dx.doi.org/10.1021/acsomega.0c05072