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Synthesis of Functionally Substituted Bicyclo[4.2.1]nona-2,4-dienes and Bicyclo[4.2.1]nona-2,4,7-trienes by Cobalt(I)-catalyzed [6π + 2π] Cycloaddition of 2-Tropylcyclohexanone
[Image: see text] The [6π + 2π] cycloaddition of 2-tropylcyclohexanone to allenes and alkynes was accomplished for the first time using the three-component catalytic system Co(acac)(2)(dppe)/Zn/ZnI(2), thus giving previously unknown functionally substituted bicyclo[4.2.1]nona-2,4-dienes and bicyclo[...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7726926/ https://www.ncbi.nlm.nih.gov/pubmed/33324856 http://dx.doi.org/10.1021/acsomega.0c05072 |