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Large Non-planar Conjugated Molecule with Strong Intermolecular Interactions Achieved with Homoleptic Zn(II) Complex of Di(5-quinolylethynyl)-tetraphenylazadipyrromethene

[Image: see text] Zinc(II) complexes of tetraphenylazadipyrromethenes are potential non-planar n-type conjugated materials. To tune the properties, we installed 5-quinolylethynyl groups at the pyrrolic positions. Compared to the complex with 1-napthylethynyl, we found evidence for stronger intermole...

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Detalles Bibliográficos
Autores principales: Lu, Chenwei, Wang, Chunlai, Jimenez, Jayvic C., Rheingold, Arnold L., Sauvé, Genevieve
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7726932/
https://www.ncbi.nlm.nih.gov/pubmed/33324859
http://dx.doi.org/10.1021/acsomega.0c05169