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Application of Green Solvents: PEG and scCO(2) in the Mono- or Biphasic Catalytic Systems for the Repetitive Batch Coupling of Vinylsilanes with Vinyl Boronates toward 1-Boryl-1-silylethenes
[Image: see text] A new method for the repetitive batch silylative coupling (trans-silylation) of vinylsilanes with vinyl boronates in the presence of Ru(CO)Cl(H)(PCy(3))(2) immobilized in poly(ethylene glycols) (PEGs) has been developed. Three PEGs (PEG600, PEG2000, and MPEG2000) with different mol...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American
Chemical Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735702/ https://www.ncbi.nlm.nih.gov/pubmed/33232139 http://dx.doi.org/10.1021/acs.inorgchem.0c02796 |