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Enantioselective Construction of Tertiary Fluoride Stereocenters by Organocatalytic Fluorocyclization

[Image: see text] 1,1-Disubstituted styrenes with internal oxygen and nitrogen nucleophiles undergo oxidative fluorocyclization reactions with in situ generated chiral iodine(III)-catalysts. The resulting fluorinated tetrahydrofurans and pyrrolidines contain a tertiary carbon–fluorine stereocenter....

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Detalles Bibliográficos
Autores principales:	Wang, Qiang, Lübcke, Marvin, Biosca, Maria, Hedberg, Martin, Eriksson, Lars, Himo, Fahmi, Szabó, Kálmán J.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2020
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735711/ https://www.ncbi.nlm.nih.gov/pubmed/33191747 http://dx.doi.org/10.1021/jacs.0c09323

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