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Mechanisms of Formation and Rearrangement of Benziodoxole-Based CF(3) and SCF(3) Transfer Reagents
[Image: see text] Togni’s benziodoxole-based reagents are widely used in trifluoromethylation reactions. It has been established that the kinetically stable hypervalent iodine form (I–CF(3)) of the reagents is thermodynamically less stable than its acyclic ether isomer (O–CF(3)). On the other hand,...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical
Society
2020
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735722/ https://www.ncbi.nlm.nih.gov/pubmed/33201704 http://dx.doi.org/10.1021/acs.joc.0c02306 |