Allyl Cyanate/Isocyanate Rearrangement in Glycals: Stereoselective Synthesis of 1-Amino and Diamino Sugar Derivatives

[Image: see text] The [3,3]-sigmatropic allyl cyanate/isocyanate rearrangement of glycals in the presence of O-, N-, and C-nucleophiles afforded β-N-glucosyl and galactosyl carbamates, ureas, and amides in good yields. The unsaturated products were elaborated to N-glycosides by dihydroxylation, to 1...

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Detalles Bibliográficos
Autores principales: Mirabella, Stefania, Petrucci, Giulia, Faggi, Cristina, Matassini, Camilla, Cardona, Francesca, Goti, Andrea
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735751/
https://www.ncbi.nlm.nih.gov/pubmed/33147974
http://dx.doi.org/10.1021/acs.orglett.0c03438

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7735751/
https://www.ncbi.nlm.nih.gov/pubmed/33147974
http://dx.doi.org/10.1021/acs.orglett.0c03438

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