Metal-free nucleophilic trifluoromethylselenolation via an iodide-mediated umpolung reactivity of trifluoromethylselenotoluenesulfonate

We report herein a practical method to generate CF(3)Se(−) (and R(F)Se(−)) anions from shelf-stable reagents under iodide activation. Metal-free nucleophilic trifluoromethylselenolations have been then performed with this in situ-generated anion. Perfluoroalkylselenolations have also been described....

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Detalles Bibliográficos
Autores principales: Grollier, Kevin, Taponard, Alexis, De Zordo-Banliat, Arnaud, Magnier, Emmanuel, Billard, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Beilstein-Institut 2020
Materias:
Full Research Paper
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7736694/
https://www.ncbi.nlm.nih.gov/pubmed/33363671
http://dx.doi.org/10.3762/bjoc.16.252

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7736694/
https://www.ncbi.nlm.nih.gov/pubmed/33363671
http://dx.doi.org/10.3762/bjoc.16.252

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