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External oxidant-compatible phosphorus(III)-directed site-selective C–H carbonylation

The first development of an external oxidant-compatible system involving a phosphorus(III)-directed C–H functionalization has been uncovered. An efficient C–H esterification of indoles with CO and alcohols has been reported in which the high reactivity and the exclusive C7-selectivity derives from t...

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Detalles Bibliográficos
Autores principales: Dong, Ben, Qian, Jiasheng, Li, Mingjie, Wang, Zheng-Jun, Wang, Minyan, Wang, Dingyi, Yuan, Chengkai, Han, Ying, Zhao, Yue, Shi, Zhuangzhi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7744084/
https://www.ncbi.nlm.nih.gov/pubmed/33328235
http://dx.doi.org/10.1126/sciadv.abd1378