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Site‐Selective C−H Oxygenation via Aryl Sulfonium Salts

Herein, we report a two‐step process forming arene C−O bonds in excellent site‐selectivity at a late‐stage. The C−O bond formation is achieved by selective introduction of a thianthrenium group, which is then converted into C−O bonds using photoredox chemistry. Electron‐rich, ‐poor and ‐neutral aren...

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Detalles Bibliográficos
Autores principales: Sang, Ruocheng, Korkis, Stamatis E., Su, Wanqi, Ye, Fei, Engl, Pascal S., Berger, Florian, Ritter, Tobias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7754133/
https://www.ncbi.nlm.nih.gov/pubmed/31475767
http://dx.doi.org/10.1002/anie.201908718