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Reversible Hydride Migration from C(5)Me(5) to Rh(I) Revealed by a Cooperative Bimetallic Approach

The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing examples of non‐innocent behaviour are being documented. Here, we provide evidence for reversible intramolecular C−H activation at one methy...

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Detalles Bibliográficos
Autores principales: Alférez, Macarena G., Moreno, Juan J., Hidalgo, Nereida, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7754342/
https://www.ncbi.nlm.nih.gov/pubmed/33448577
http://dx.doi.org/10.1002/anie.202008442