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Reversible Hydride Migration from C(5)Me(5) to Rh(I) Revealed by a Cooperative Bimetallic Approach
The use of cyclopentadienyl ligands in organometallic chemistry and catalysis is ubiquitous, mostly due to their robust spectator role. Nonetheless, increasing examples of non‐innocent behaviour are being documented. Here, we provide evidence for reversible intramolecular C−H activation at one methy...
Autores principales: | Alférez, Macarena G., Moreno, Juan J., Hidalgo, Nereida, Campos, Jesús |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7754342/ https://www.ncbi.nlm.nih.gov/pubmed/33448577 http://dx.doi.org/10.1002/anie.202008442 |
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