Aryl Sulfonium Salts for Site‐Selective Late‐Stage Trifluoromethylation

Incorporation of the CF(3) group into arenes has found increasing importance in drug discovery. Herein, we report the first photoredox‐catalyzed cross‐coupling of aryl thianthrenium salts with a copper‐based trifluoromethyl reagent, which enables a site‐selective late‐stage trifluoromethylation of a...

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Detalles Bibliográficos
Autores principales: Ye, Fei, Berger, Florian, Jia, Hao, Ford, Joseph, Wortman, Alan, Börgel, Jonas, Genicot, Christophe, Ritter, Tobias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7754511/
https://www.ncbi.nlm.nih.gov/pubmed/31389649
http://dx.doi.org/10.1002/anie.201906672

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7754511/
https://www.ncbi.nlm.nih.gov/pubmed/31389649
http://dx.doi.org/10.1002/anie.201906672

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