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Synthesis‐Controlled Polymorphism and Optical Properties of Phyllosilicate‐Analogous Borosulfates M[B(2)(SO(4))(4)] (M=Mg, Co)
Increased synthetic control in borosulfate chemistry leads to the access of various new compounds. Herein, the polymorphism of phyllosilicate‐analogous borosulfates is unraveled by adjusting the oleum (65 % SO(3)) content. The new polymorphs β‐Mg[B(2)(SO(4))(4)] and α‐Co[B(2)(SO(4))(4)] both consist...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756226/ https://www.ncbi.nlm.nih.gov/pubmed/32744744 http://dx.doi.org/10.1002/chem.202003214 |