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Synthesis‐Controlled Polymorphism and Optical Properties of Phyllosilicate‐Analogous Borosulfates M[B(2)(SO(4))(4)] (M=Mg, Co)

Increased synthetic control in borosulfate chemistry leads to the access of various new compounds. Herein, the polymorphism of phyllosilicate‐analogous borosulfates is unraveled by adjusting the oleum (65 % SO(3)) content. The new polymorphs β‐Mg[B(2)(SO(4))(4)] and α‐Co[B(2)(SO(4))(4)] both consist...

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Detalles Bibliográficos
Autores principales:	Netzsch, Philip, Pielnhofer, Florian, Glaum, Robert, Höppe, Henning A.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Full Papers
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756226/ https://www.ncbi.nlm.nih.gov/pubmed/32744744 http://dx.doi.org/10.1002/chem.202003214

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