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NHCs as Neutral Donors towards Polyphosphorus Complexes

The first adducts of NHCs (=N‐heterocyclic carbenes) with aromatic polyphosphorus complexes are reported. The reactions of [Cp*Fe(η(5)‐P(5))] (1) (Cp*=pentamethyl‐cyclopentadienyl) with IMe (=1,3,4,5‐tetramethylimidazolin‐2‐ylidene), IMes (=1,3‐bis(2,4,6‐trimethylphenyl)‐imidazolin‐2‐ylidene) and ID...

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Detalles Bibliográficos
Autores principales: Riedlberger, Felix, Todisco, Stefano, Mastrorilli, Piero, Timoshkin, Alexey Y., Seidl, Michael, Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756228/
https://www.ncbi.nlm.nih.gov/pubmed/32745336
http://dx.doi.org/10.1002/chem.202003393