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Isolable Diaminophosphide Boranes

Metalation of secondary diaminophosphine boranes by alkali metal amides provides a robust and selective access route to a range of metal diaminophosphide boranes M[(R(2)N)(2)P(BH(3))] (M=Li, Na, K; R=alkyl, aryl) with acyclic or heterocyclic molecular backbones, whereas reduction of a chlorodiaminop...

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Detalles Bibliográficos
Autores principales: Blum, Markus, Dunaj, Tobias, Knöller, Julius A., Feil, Christoph M., Nieger, Martin, Gudat, Dietrich
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756230/
https://www.ncbi.nlm.nih.gov/pubmed/32567741
http://dx.doi.org/10.1002/chem.202002296