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The Cyclohexa‐2,5‐dienyl Group as a Placeholder for Hydrogen: Organocatalytic Michael Addition of an Acetaldehyde Surrogate
An aldehyde with a cyclohexa‐2,5‐dienyl group in the α‐position is introduced as a storable surrogate of highly reactive acetaldehyde. The cyclohexa‐2,5‐dienyl unit is compatible with an enantioselective Michael addition to nitroalkenes promoted by a Hayashi–Jørgensen catalyst and can be removed by...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756304/ https://www.ncbi.nlm.nih.gov/pubmed/32808731 http://dx.doi.org/10.1002/chem.202003764 |