Highly Conjugated π‐Systems Arising from Cannibalistic Hexadehydro‐Diels–Alder Couplings: Cleavage of C−C Single and Triple Bonds

We have investigated the cannibalistic self‐trapping reaction of an ortho‐benzyne derivative generated from 1,11‐bis(p‐tolyl)undeca‐1,3,8,10‐tetrayne in an HDDA reaction. Without adding any specific trapping agent, the highly reactive benzyne is trapped by another bisdiyne molecule in at least three...

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Detalles Bibliográficos
Autores principales: Maier, Jan, Deutsch, Marian, Merz, Julia, Ye, Qing, Diamond, Oliver, Schilling, Maja‐Tessa, Friedrich, Alexandra, Engels, Bernd, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756338/
https://www.ncbi.nlm.nih.gov/pubmed/32619049
http://dx.doi.org/10.1002/chem.202002511

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756338/
https://www.ncbi.nlm.nih.gov/pubmed/32619049
http://dx.doi.org/10.1002/chem.202002511

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