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Highly Conjugated π‐Systems Arising from Cannibalistic Hexadehydro‐Diels–Alder Couplings: Cleavage of C−C Single and Triple Bonds
We have investigated the cannibalistic self‐trapping reaction of an ortho‐benzyne derivative generated from 1,11‐bis(p‐tolyl)undeca‐1,3,8,10‐tetrayne in an HDDA reaction. Without adding any specific trapping agent, the highly reactive benzyne is trapped by another bisdiyne molecule in at least three...
| Autores principales: | , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756338/ https://www.ncbi.nlm.nih.gov/pubmed/32619049 http://dx.doi.org/10.1002/chem.202002511 |