Mechanism of 3‐Methylglutaconyl CoA Decarboxylase AibA/AibB: Pericyclic Reaction versus Direct Decarboxylation

The enzyme 3‐methylglutaconyl coenzyme A (CoA) decarboxylase (called AibA/AibB) catalyzes the decarboxylation of 3‐methylglutaconyl CoA to generate 3,3‐dimethylacrylyl‐CoA, representing an important step in the biosynthesis of isovaleryl‐coenzyme A in Myxococcus xanthus when the regular pathway is b...

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Detalles Bibliográficos
Autores principales: Sheng, Xiang, Himo, Fahmi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756340/
https://www.ncbi.nlm.nih.gov/pubmed/32914510
http://dx.doi.org/10.1002/anie.202008919

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756340/
https://www.ncbi.nlm.nih.gov/pubmed/32914510
http://dx.doi.org/10.1002/anie.202008919

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