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Conformation and Aromaticity Switching in a Curved Non‐Alternant sp(2) Carbon Scaffold

A curved sp(2) carbon scaffold containing fused pentagon and heptagon units (1) was synthesized by Pd‐catalyzed [5+2] annulation from a 3,9‐diboraperylene precursor and shows two reversible oxidation processes at low redox potential, accompanied by a butterfly‐like motion. Stepwise oxidation produce...

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Detalles Bibliográficos
Autores principales: Zhu, Chongwei, Shoyama, Kazutaka, Würthner, Frank
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756343/
https://www.ncbi.nlm.nih.gov/pubmed/32815658
http://dx.doi.org/10.1002/anie.202010077