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Conformation and Aromaticity Switching in a Curved Non‐Alternant sp(2) Carbon Scaffold
A curved sp(2) carbon scaffold containing fused pentagon and heptagon units (1) was synthesized by Pd‐catalyzed [5+2] annulation from a 3,9‐diboraperylene precursor and shows two reversible oxidation processes at low redox potential, accompanied by a butterfly‐like motion. Stepwise oxidation produce...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756343/ https://www.ncbi.nlm.nih.gov/pubmed/32815658 http://dx.doi.org/10.1002/anie.202010077 |