A Chatt‐Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia

With [Mo(N(2))(P(2) (Me)PP(2) (Ph))] the first Chatt‐type complex with one coordination site catalytically converting N(2) to ammonia is presented. Employing SmI(2) as reductant and H(2)O as proton source 26 equivalents of ammonia are generated. Analogous Mo(0)‐N(2) complexes supported by a combinat...

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Detalles Bibliográficos
Autores principales: Engesser, Tobias A., Kindjajev, Andrei, Junge, Jannik, Krahmer, Jan, Tuczek, Felix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756349/
https://www.ncbi.nlm.nih.gov/pubmed/32815654
http://dx.doi.org/10.1002/chem.202003549

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756349/
https://www.ncbi.nlm.nih.gov/pubmed/32815654
http://dx.doi.org/10.1002/chem.202003549

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