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A Chatt‐Type Catalyst with One Coordination Site for Dinitrogen Reduction to Ammonia
With [Mo(N(2))(P(2) (Me)PP(2) (Ph))] the first Chatt‐type complex with one coordination site catalytically converting N(2) to ammonia is presented. Employing SmI(2) as reductant and H(2)O as proton source 26 equivalents of ammonia are generated. Analogous Mo(0)‐N(2) complexes supported by a combinat...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756349/ https://www.ncbi.nlm.nih.gov/pubmed/32815654 http://dx.doi.org/10.1002/chem.202003549 |