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α‐Cationic Phospholes: Synthesis and Applications as Ancillary Ligands

A series of structurally differentiated α‐cationic phospholes containing cyclopropenium, imidazolium, and iminium substituents has been synthesized by reaction of chlorophosphole 1 with the corresponding stable carbenes. Evaluation of the donor properties of these compounds reveals that their strong...

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Detalles Bibliográficos
Autores principales: Johannsen, Tim, Golz, Christopher, Alcarazo, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756421/
https://www.ncbi.nlm.nih.gov/pubmed/32853445
http://dx.doi.org/10.1002/anie.202009303