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Metal/Metal Redox Isomerism Governed by Configuration
A pair of diastereomeric dinuclear complexes, [Tp′(CO)BrW{μ‐η(2)‐C,C′‐κ(2)‐S,P‐C(2)(PPh(2))S}Ru(η(5)‐C(5)H(5))(PPh(3))], in which W and Ru are bridged by a phosphinyl(thiolato)alkyne in a side‐on carbon P,S‐chelate coordination mode, were synthesized, separated and fully characterized. Even though t...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756430/ https://www.ncbi.nlm.nih.gov/pubmed/32648996 http://dx.doi.org/10.1002/chem.202003120 |