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Metal/Metal Redox Isomerism Governed by Configuration

A pair of diastereomeric dinuclear complexes, [Tp′(CO)BrW{μ‐η(2)‐C,C′‐κ(2)‐S,P‐C(2)(PPh(2))S}Ru(η(5)‐C(5)H(5))(PPh(3))], in which W and Ru are bridged by a phosphinyl(thiolato)alkyne in a side‐on carbon P,S‐chelate coordination mode, were synthesized, separated and fully characterized. Even though t...

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Detalles Bibliográficos
Autores principales: Ludwig, Stephan, Helmdach, Kai, Hüttenschmidt, Mareike, Oberem, Elisabeth, Rabeah, Jabor, Villinger, Alexander, Ludwig, Ralf, Seidel, Wolfram W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756430/
https://www.ncbi.nlm.nih.gov/pubmed/32648996
http://dx.doi.org/10.1002/chem.202003120

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