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A Toroidal Zr(70) Oxysulfate Cluster and Its Diverse Packing Structures

Herein, we report the discovery of a toroidal inorganic cluster of zirconium(IV) oxysulfate of unprecedented size with the formula Zr(70)(SO(4))(58)(O/OH)(146)⋅x(H(2)O) (Zr(70)), which displays different packing of ring units and thus several polymorphic crystal structures. The ring measures over 3 ...

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Detalles Bibliográficos
Autores principales: Øien‐Ødegaard, Sigurd, Bazioti, Calliope, Redekop, Evgeniy A., Prytz, Øystein, Lillerud, Karl Petter, Olsbye, Unni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756470/
https://www.ncbi.nlm.nih.gov/pubmed/32902113
http://dx.doi.org/10.1002/anie.202010847