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Fluoro Nitrenoid Complexes FN=MF(2) (M=Co, Rh, Ir): Electronic Structure Dichotomy and Formation of Nitrido Fluorides N≡MF(3)
The fluoronitrenoid metal complexes FNCoF(2) and FNRhF(2) as well as the first ternary Rh(VI) and Ir(VI) complexes NIrF(3) and NRhF(3) are described. They were obtained by the reaction of excited Group‐9 metal atoms with NF(3) and their IR spectra, isolated in solid rare gases (neon and argon), were...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756499/ https://www.ncbi.nlm.nih.gov/pubmed/32886443 http://dx.doi.org/10.1002/anie.202010950 |