Closed Shell Iron(IV) Oxo Complex with an Fe–O Triple Bond: Computational Design, Synthesis, and Reactivity

Iron(IV)‐oxo intermediates in nature contain two unpaired electrons in the Fe–O antibonding orbitals, which are thought to contribute to their high reactivity. To challenge this hypothesis, we designed and synthesized closed‐shell singlet iron(IV) oxo complex [(quinisox)Fe(O)](+) (1(+); quinisox‐H=(...

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Detalles Bibliográficos
Autores principales: Andris, Erik, Segers, Koen, Mehara, Jaya, Rulíšek, Lubomír, Roithová, Jana
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756500/
https://www.ncbi.nlm.nih.gov/pubmed/32926539
http://dx.doi.org/10.1002/anie.202009347

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756500/
https://www.ncbi.nlm.nih.gov/pubmed/32926539
http://dx.doi.org/10.1002/anie.202009347

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