Terminal Alkyne Coupling Reactions Through a Ring: Effect of Ring Size on Rate and Regioselectivity

Terminal alkyne coupling reactions promoted by rhodium(I) complexes of macrocyclic NHC‐based pincer ligands—which feature dodecamethylene, tetradecamethylene or hexadecamethylene wingtip linkers viz. [Rh(CNC‐n)(C(2)H(4))][BAr(F) (4)] (n=12, 14, 16; Ar(F)=3,5‐(CF(3))(2)C(6)H(3))—have been investigate...

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Detalles Bibliográficos
Autores principales: Storey, Caroline M., Gyton, Matthew R., Andrew, Rhiann E., Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756505/
https://www.ncbi.nlm.nih.gov/pubmed/32677713
http://dx.doi.org/10.1002/chem.202002962

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756505/
https://www.ncbi.nlm.nih.gov/pubmed/32677713
http://dx.doi.org/10.1002/chem.202002962

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