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Isolable Silicon‐Based Polycations with Lewis Superacidity
Molecular silicon polycations of the types R(2)Si(2+) and RSi(3+) (R=H, organic groups) are elusive Lewis superacids and currently unknown in the condensed phase. Here, we report the synthesis of a series of isolable terpyridine‐stabilized R(2)Si(2+) and RSi(3+) complexes, [R(2)Si(terpy)](2+) (R=Ph...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756528/ https://www.ncbi.nlm.nih.gov/pubmed/32935903 http://dx.doi.org/10.1002/anie.202011696 |