Visible Light‐Enabled sp(3)‐C−H Functionalization with Chloro‐ and Bromoalkynes: Chemoselective Route to Vinylchlorides or Alkynes

An unprecedented direct atom‐economic chemo‐ and regioselective hydroalkylation of chloroalkynes and an sp(3)‐C−H alkynylation of bromoalkynes was achieved. The reaction partners are unfunctionalized ethers, alcohols, amides, and even non‐activated hydrocarbons. We found that a household fluorescent...

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Detalles Bibliográficos
Autores principales: Adak, Tapas, Hoffmann, Marvin, Witzel, Sina, Rudolph, Matthias, Dreuw, Andreas, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756539/
https://www.ncbi.nlm.nih.gov/pubmed/32472581
http://dx.doi.org/10.1002/chem.202001259

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756539/
https://www.ncbi.nlm.nih.gov/pubmed/32472581
http://dx.doi.org/10.1002/chem.202001259

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