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Molecular Zinc Hydride Cations [ZnH](+): Synthesis, Structure, and CO(2) Hydrosilylation Catalysis

Protonolysis of [ZnH(2)](n) with the conjugated Brønsted acid of the bidentate diamine TMEDA (N,N,N′,N′‐tetramethylethane‐1,2‐diamine) and TEEDA (N,N,N′,N′‐tetraethylethane‐1,2‐diamine) gave the zinc hydride cation [(L(2))ZnH](+), isolable either as the mononuclear THF adduct [(L(2))ZnH(thf)](+)[BAr...

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Detalles Bibliográficos
Autores principales: Ritter, Florian, Spaniol, Thomas P., Douair, Iskander, Maron, Laurent, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756573/
https://www.ncbi.nlm.nih.gov/pubmed/32931656
http://dx.doi.org/10.1002/anie.202011480