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Molecular Zinc Hydride Cations [ZnH](+): Synthesis, Structure, and CO(2) Hydrosilylation Catalysis
Protonolysis of [ZnH(2)](n) with the conjugated Brønsted acid of the bidentate diamine TMEDA (N,N,N′,N′‐tetramethylethane‐1,2‐diamine) and TEEDA (N,N,N′,N′‐tetraethylethane‐1,2‐diamine) gave the zinc hydride cation [(L(2))ZnH](+), isolable either as the mononuclear THF adduct [(L(2))ZnH(thf)](+)[BAr...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756573/ https://www.ncbi.nlm.nih.gov/pubmed/32931656 http://dx.doi.org/10.1002/anie.202011480 |