Bis(silylene)‐Stabilized Monovalent Nitrogen Complexes

The first series of bis(silylene)‐stabilized nitrogen(I) compounds is described. Starting from the 1,2‐bis(N‐heterocyclic silylenyl) 1,2‐dicarba‐closo‐dedocaborane(12) scaffold 1, [1,2‐(LSi)(2)C(2)B(10)H(10); L=PhC(N(t)Bu)(2)], reaction with adamantyl azide (AdN(3)) affords the terminal N‐μ(2)‐bridg...

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Detalles Bibliográficos
Autores principales: Yao, Shenglai, Szilvási, Tibor, Xiong, Yun, Lorent, Christian, Ruzicka, Ales, Driess, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756627/
https://www.ncbi.nlm.nih.gov/pubmed/32841449
http://dx.doi.org/10.1002/anie.202011598

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756627/
https://www.ncbi.nlm.nih.gov/pubmed/32841449
http://dx.doi.org/10.1002/anie.202011598

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