Cargando…

Bis(silylene)‐Stabilized Monovalent Nitrogen Complexes

The first series of bis(silylene)‐stabilized nitrogen(I) compounds is described. Starting from the 1,2‐bis(N‐heterocyclic silylenyl) 1,2‐dicarba‐closo‐dedocaborane(12) scaffold 1, [1,2‐(LSi)(2)C(2)B(10)H(10); L=PhC(N(t)Bu)(2)], reaction with adamantyl azide (AdN(3)) affords the terminal N‐μ(2)‐bridg...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yao, Shenglai, Szilvási, Tibor, Xiong, Yun, Lorent, Christian, Ruzicka, Ales, Driess, Matthias
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2020
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756627/ https://www.ncbi.nlm.nih.gov/pubmed/32841449 http://dx.doi.org/10.1002/anie.202011598

Ejemplares similares

Changing the Reactivity of Zero‐ and Mono‐Valent Germanium with a Redox Non‐Innocent Bis(silylenyl)carborane Ligand
por: Yao, Shenglai, et al.
Publicado: (2021)

A Genuine Stannylone with a Monoatomic Two‐Coordinate Tin(0) Atom Supported by a Bis(silylene) Ligand
por: Xu, Jian, et al.
Publicado: (2021)

Unexpected White Phosphorus (P(4)) Activation Modes with Silylene‐Substituted o‐Carboranes and Access to an Isolable 1,3‐Diphospha‐2,4‐disilabutadiene
por: Xiong, Yun, et al.
Publicado: (2022)

A Striking Mode of Activation of Carbon Disulfide with a Cooperative Bis(silylene)
por: Luecke, Marcel‐Philip, et al.
Publicado: (2021)

A bis(silylene)pyridine pincer ligand can stabilize mononuclear manganese(0) complexes: facile access to isolable analogues of the elusive d(7)-Mn(CO)(5) radical
por: Kalra, Shweta, et al.
Publicado: (2022)

Cycloaddition Chemistry of a Silylene‐Nickel Complex toward Organic π‐Systems: From Reversibility to C−H Activation
por: Hadlington, Terrance J., et al.
Publicado: (2020)

Stimuli Responsive Silylene: Electromerism Induced Reversible Switching Between Mono‐ and Bis‐Silylene
por: Yadav, Ravi, et al.
Publicado: (2022)

An Isolable Bis(Silanone–Borane) Adduct
por: Luecke, Marcel‐Philip, et al.
Publicado: (2020)

The Heaviest Bottleable Metallylone: Synthesis of a Monatomic, Zero‐Valent Lead Complex (“Plumbylone”)
por: Xu, Jian, et al.
Publicado: (2022)

DMAP-stabilized bis(silyl)silylenes as versatile synthons for organosilicon compounds
por: Holzner, Richard, et al.
Publicado: (2020)

Open-Shell Lanthanide(II+) or -(III+) Complexes Bearing σ-Silyl and Silylene Ligands: Synthesis, Structure, and Bonding Analysis
por: Zitz, Rainer, et al.
Publicado: (2015)

A Silylene Stabilized by a σ‐Donating Nickel(0) Fragment
por: Frutos, María, et al.
Publicado: (2022)

Stabilization of Reactive Nitrene by Silylenes without Using a Reducing Metal
por: Ding, Yi, et al.
Publicado: (2021)

Generation of Bis(ferrocenyl)silylenes from Siliranes †
por: Pan, Yang, et al.
Publicado: (2020)

Synthesis and Reactivity of Bis(silylene)‐Coordinated Calcium and Divalent Lanthanide Complexes
por: Sun, Xiaofei, et al.
Publicado: (2020)

Isolation and characterization of bis(silylene)-stabilized antimony(I) and bismuth(I) cations
por: Wang, Xuyang, et al.
Publicado: (2023)

Boosting homogeneous chemoselective hydrogenation of olefins mediated by a bis(silylenyl)terphenyl-nickel(0) pre-catalyst
por: Lücke, Marcel-Philip, et al.
Publicado: (2021)

Peripheral mechanism of a carbonyl hydrosilylation catalysed by an SiNSi iron pincer complex
por: Metsänen, Toni T., et al.
Publicado: (2015)

An Isolable 2,5‐Disila‐3,4‐Diphosphapyrrole and a Conjugated Si=P−Si=P−Si=N Chain Through Degradation of White Phosphorus with a N,N‐Bis(Silylenyl)Aniline
por: Xiong, Yun, et al.
Publicado: (2022)

From an Fe(2)P(3) complex to FeP nanoparticles as efficient electrocatalysts for water-splitting
por: Yao, Shenglai, et al.
Publicado: (2018)

A silylene-stabilized ditin(0) complex and its conversion to methylditin cation and distannavinylidene
por: Du, Shaozhi, et al.
Publicado: (2023)

Striking transformations of the hydroborylene ligand in a HB:→Ni(II) complex with isocyanides and CO
por: Hadlington, T. J., et al.
Publicado: (2018)

Interconversion and reactivity of manganese silyl, silylene, and silene complexes
por: Price, Jeffrey S., et al.
Publicado: (2019)

Heavier congeners of CO and CO(2) as ligands: from zero-valent germanium (‘germylone’) to isolable monomeric GeX and GeX(2) complexes (X = S, Se, Te)
por: Xiong, Yun, et al.
Publicado: (2016)

Treatment of Silylene–Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon‐Bonded Chalcogens
por: Sinhababu, Soumen, et al.
Publicado: (2019)

A Stable N‐Heterocyclic Silylene with a 1,1′‐Ferrocenediyl Backbone
por: Weyer, Nadine, et al.
Publicado: (2020)

Synthesis and Characterization of Block Copolymers of Poly(silylene diethynylbenzen) and Poly(silylene dipropargyl aryl ether)
por: Gao, Man, et al.
Publicado: (2021)

Reactivity of a Unique Si(I)–Si(I)-Based η(2)-Bis(silylene) Iron Complex
por: He, Zhiyuan, et al.
Publicado: (2022)

Synthesis and Reactivity of a Neutral Homocyclic Silylene
por: Keuter, Jan, et al.
Publicado: (2021)

Substituent Effects of Phenyl Group on Silylene Bridge in Stereospecific Polymerization of Propylene with C(1)-Symmetric Ansa-Silylene(fluorenyl)(amido) Dimethyl Titanium Complexes
por: Wang, Huajin, et al.
Publicado: (2018)

Small Molecule Activation by Two‐Coordinate Acyclic Silylenes
por: Fujimori, Shiori, et al.
Publicado: (2020)

Isolation and Reactivity of Tetrylene‐Tetrylone‐Iron Complexes Supported by Bis(N‐Heterocyclic Imine) Ligands
por: Zhao, Xuan‐Xuan, et al.
Publicado: (2022)

Taming a monomeric [Cu(η(6)-C(6)H(6))](+) complex with silylene
por: Parvin, Nasrina, et al.
Publicado: (2018)

Monovalent lanthanide(I) in borozene complexes
por: Li, Wan-Lu, et al.
Publicado: (2021)

Reversible Isomerization Between Silacyclopropyl Cation and Cyclic (Alkyl)(Amino)Silylene
por: Nougué, Raphaël, et al.
Publicado: (2022)

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines
por: Ochiai, Tatsumi, et al.
Publicado: (2016)

An Isolable Three‐Coordinate Germanone and Its Reactivity
por: Zhao, Xuan‐Xuan, et al.
Publicado: (2021)

N‐Heterocyclic Silylenes as Ligands in Transition Metal Carbonyl Chemistry: Nature of Their Bonding and Supposed Innocence
por: Krahfuß, Mirjam J., et al.
Publicado: (2020)

Isolable Silicon‐Based Polycations with Lewis Superacidity
por: Hermannsdorfer, André, et al.
Publicado: (2020)

Silicon Tetrakis(trifluoromethanesulfonate): A Simple Neutral Silane Acting as a Soft and Hard Lewis Superacid
por: Hermannsdorfer, André, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_fiorkm5773vk23gl3g9mm6p0it