Oxidative Addition of a Mechanically Entrapped C(sp)–C(sp) Bond to a Rhodium(I) Pincer Complex

By use of a macrocyclic phosphinite pincer ligand and bulky substrate substituents, we demonstrate how the mechanical bond can be leveraged to promote the oxidative addition of an interlocked 1,3‐diyne to a rhodium(I) center. The resulting rhodium(III) bis(alkynyl) product can be trapped out by reac...

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Detalles Bibliográficos
Autores principales: Leforestier, Baptiste, Gyton, Matthew R., Chaplin, Adrian B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756736/
https://www.ncbi.nlm.nih.gov/pubmed/32929831
http://dx.doi.org/10.1002/anie.202009546

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756736/
https://www.ncbi.nlm.nih.gov/pubmed/32929831
http://dx.doi.org/10.1002/anie.202009546

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