Rhodium‐Catalyzed Cyclization of Terminal and Internal Allenols: An Atom Economic and Highly Stereoselective Access Towards Tetrahydropyrans

A comprehensive study of a diastereoselective Rh‐catalyzed cyclization of terminal and internal allenols is reported. The methodology allows the atom economic and highly syn‐selective access to synthetically important 2,4‐disubstituted and 2,4,6‐trisubstituted tetrahydropyrans (THP). Furthermore, it...

Descripción completa

Detalles Bibliográficos
Autores principales: Schmidt, Johannes P., Breit, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756761/
https://www.ncbi.nlm.nih.gov/pubmed/32940396
http://dx.doi.org/10.1002/anie.202009166

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756761/
https://www.ncbi.nlm.nih.gov/pubmed/32940396
http://dx.doi.org/10.1002/anie.202009166

Ejemplares similares