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A Neutral Three‐Membered 2π Aromatic Disilaborirane and the Unique Conversion into a Four‐Membered BSi(2)N‐Ring
We report the design, synthesis, structure, bonding, and reaction of a neutral 2π aromatic three‐membered disilaborirane. The disilaborirane is synthesized by a facile one‐pot reductive dehalogenation of amidinato‐silylene chloride and dibromoarylborane with potassium graphite. Despite the tetravale...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756765/ https://www.ncbi.nlm.nih.gov/pubmed/32840959 http://dx.doi.org/10.1002/anie.202009638 |