Two‐Step Synthesis of Heptacyclo[6.6.0.0(2,6).0(3,13).0(4,11).0(5,9).0(10,14)] tetradecane from Norbornadiene: Mechanism of the Cage Assembly and Post‐synthetic Functionalization

A selective and scalable two‐step approach to the dimerization of norbornadiene (NBD) into its thermodynamically most stable dimer, heptacyclo[6.6.0.0(2,6).0(3,13).0(4,11).0(5,9).0(10,14)] tetradecane, (HCTD) is reported. Calculations indicate that the reaction starts with the Rh‐catalyzed stepwise...

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Detalles Bibliográficos
Autores principales: Zieliński, Adam, Marset, Xavier, Golz, Christopher, Wolf, Lawrence M., Alcarazo, Manuel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756769/
https://www.ncbi.nlm.nih.gov/pubmed/32881255
http://dx.doi.org/10.1002/anie.202010766

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756769/
https://www.ncbi.nlm.nih.gov/pubmed/32881255
http://dx.doi.org/10.1002/anie.202010766

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