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Two‐Step Synthesis of Heptacyclo[6.6.0.0(2,6).0(3,13).0(4,11).0(5,9).0(10,14)] tetradecane from Norbornadiene: Mechanism of the Cage Assembly and Post‐synthetic Functionalization
A selective and scalable two‐step approach to the dimerization of norbornadiene (NBD) into its thermodynamically most stable dimer, heptacyclo[6.6.0.0(2,6).0(3,13).0(4,11).0(5,9).0(10,14)] tetradecane, (HCTD) is reported. Calculations indicate that the reaction starts with the Rh‐catalyzed stepwise...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2020
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756769/ https://www.ncbi.nlm.nih.gov/pubmed/32881255 http://dx.doi.org/10.1002/anie.202010766 |