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Photocatalytic CO(2) Reductions Catalyzed by meso‐(1,10‐Phenanthrolin‐2‐yl)‐Porphyrins Having a Rhenium(I) Tricarbonyl Complex

We have prepared Zn and free‐base porphyrins appended with a fac‐Re(phen)(CO)(3)Br (where phen is 1,10‐phenanthroline) at the meso position of the porphyrin, and performed photocatalytic CO(2) reduction using porphyrin–Re dyads in the presence of either triethylamine (TEA) or 1,3‐dimethyl‐2‐phenyl‐2...

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Detalles Bibliográficos
Autores principales: Kuramochi, Yusuke, Satake, Akiharu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756820/
https://www.ncbi.nlm.nih.gov/pubmed/32726503
http://dx.doi.org/10.1002/chem.202002558