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Efficient Blue Phosphorescence in Gold(I)‐Acetylide Functionalized Coinage Metal Bis(amidinate) Complexes

The synthesis of linear symmetric ethynyl‐ and acetylide‐amidinates of the coinage metals is presented. Starting with the desilylation of the complexes [{Me(3)SiC≡CC(NDipp)(2)}(2)M(2)] (Dipp=2,6‐diisopropylphenyl) (M=Cu, Au) it is demonstrated that this compound class is suitable to serve as a versa...

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Detalles Bibliográficos
Autores principales: Feuerstein, Thomas J., Seifert, Tim P., Jung, André P., Müller, Rouven, Lebedkin, Sergei, Kappes, Manfred M., Roesky, Peter W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7756867/
https://www.ncbi.nlm.nih.gov/pubmed/32520425
http://dx.doi.org/10.1002/chem.202002466