Organocatalytic Synthesis of α-Trifluoromethyl Allylboronic Acids by Enantioselective 1,2-Borotropic Migration

[Image: see text] Chiral α-substituted allylboronic acids were synthesized by asymmetric homologation of alkenylboronic acids using CF(3)/TMS-diazomethanes in the presence of BINOL catalyst and ethanol. The chiral α-substituted allylboronic acids were reacted with aldehydes or oxidized to alcohols i...

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Detalles Bibliográficos
Autores principales: Jonker, Sybrand J. T., Jayarajan, Ramasamy, Kireilis, Tautvydas, Deliaval, Marie, Eriksson, Lars, Szabó, Kálmán J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7760092/
https://www.ncbi.nlm.nih.gov/pubmed/33270462
http://dx.doi.org/10.1021/jacs.0c09923

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7760092/
https://www.ncbi.nlm.nih.gov/pubmed/33270462
http://dx.doi.org/10.1021/jacs.0c09923

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